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Peter D. Hicks, David A. Grattan, Phil M. White, and Kurt M. Bayburt
Feedwater Redox Stress Management: A Detailed @T ORP™ Study at a Coal-Fired Electric Utility
Arizona Electric Power Cooperative Inc. (AEPCO), located in Cochise, Arizona, has several coal-fired electric power boilers. The boiler systems have copper-based feedwater heaters. The plant feeds carbohydrazide (ELIMIN-OX®) as its oxygen scavenger and metal passivator.
AEPCO is constantly looking for ways to improve their boiler operation and protect their capital investment. In 2006, AEPCO began an evaluation of Nalco Company's new, innovative @T ORP™ sensor technology. This technology has the ability to measure the oxidation-reduction potential of feedwater at system operating temperatures and pressures.
Monitoring and controlling the feedwater oxidation-reduction potential at system temperature and pressure was successfully demonstrated at AEPCO. A quantum improvement (paradigm shift) in redox (reduction/oxidation) stress management was achieved after the plant switched to controlled feed of carbohydrazide based on the at-temperature (@T) ORP signal. The sensitivity, responsiveness and reliability of this technology were shown during the yearlong evaluation. At-temperature ORP (ORP(T)) showed excellent sensitivity in picking up even small changes in redox stress, providing early detection of a corrosive situation and a means of correcting it. Room temperature (RT) ORP probes were found to be relatively ineffective in picking up these feedwater (FW) redox excursions as compared to ORP(T) probes.
PowerPlant Chemistry 2006, 9 (6)
Matthew R. Freije
Around the Legionella World in 20 Minutes
This paper provides a brief update on Legionella guidelines, risk reduction strategies, legal issues, and domestic water disinfection, with recommendations for facility operators and water treatment specialists.
PowerPlant Chemistry 2006, 9 (6)
Akira Morita, Takaya Hisamatsu, and Takahiko Uchida
Recent Status of Legionella Issues in Japan
The "Japanese Guideline for the Prevention of Legionellosis" is introduced and the status of Legionella inhibition in cooling water systems in Japan is reviewed. About 9,000 sampling data on Legionella in cooling water systems are discussed. A seasonal trend has been observed based on cooling water sample numbers and positive Legionella findings. Moreover, the percentage of positive findings with a registered chemical treatment program at the Japanese Association of Air Conditioning Water Treatment Chemicals for Legionella is about half that without chemical treatment. It is concluded that the registered chemical treatment program is successful in Japan.
PowerPlant Chemistry 2006, 9 (6)
George Licina
Corrosion of Service Water Piping in Nuclear Systems
Service water systems are a critical part of the infrastructure of nuclear plants. Corrosion has been shown to be the predominant degradation mechanism for service water piping. Because of the diversity of water sources (seawater, brackish water, and various fresh waters), piping materials (bare carbon steel, coated or lined carbon steel, stainless steels, and non-ferrous metals), and service water system designs, a guideline for service water piping requires a set of concise rules, rather than a prescriptive chemical "recipe," for the system to achieve its design life.
PowerPlant Chemistry 2006, 9 (6)
Albert Bursik
Organic Plant Cycle Treatment Is Becoming More Attractive
On May 22–23, 2007 the PowerPlant Chemistry Seminar "Organic Cycle Treatment Chemicals" was held in Heidelberg, Germany. This paper gives a short review of the seminar with brief summaries of the individual seminar contributions.
PowerPlant Chemistry 2006, 9 (6)
Zdenek Kadlec, Bohumir Cech, Václav Roubícek, and Pavel Kolat
Diagnostic Methods for Operating Surveillance of Large Fluidized Bed Boilers
The articles gives a summary of the measurement units that are used for diagnostic measurements in fluidized bed boilers. During the verification process, the Technical University of Ostrava designed and tested various types of probes for temperature and velocity measurements, and for sampling both flue gases and solid particles. The results give more detailed information about the behaviour of the fluidized layer in various fluidized bed boilers. Moreover they can be of use in case of boiler modifications or boiler operation improvements.
PowerPlant Chemistry 2006, 9 (6)
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